Records show they’re from Plainfield, Illinois

Grignard reagents react with carbon dioxide (either in the gaseous form, which is bubbled through the solution, or as the solid dry ice) to give magnesium salts of carboxylic acids, which are converted to the acids themselves upon treatment with acid: RMgBr + CO2 RCOO +MgBr + HCl RCOOH. Unlike the methods previously mentioned, this method adds one carbon atom to the carbon skeleton. The two procedures are complementary.

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